A grim-faced Shakira was forced to endure ridicule from Brazil fans seated around her moments after the Spain centre-back was dismissed during the second half for a professional foul on Neymar.
A number of fans waved and gesticulated in her direction.
Pics: Sidharth Shukla-Rashami Desai's sizzling chemistry at TV show launch
Ooh La Lana! WWE Diva flaunts sexy curves in these 30 pictures
Photos: Salman Khan returns from Jodhpur to Mumbai
15 'peach' perfect photos of Priyanka Chopra at People's Choice Awards 2017
62 going on 16: These photos of Rekha prove she is 'forever young'